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Roll Flo Stencil Kit

USA The Hitt Companies, Inc. www.HittMarking.com USA

Page 1/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

1 Identification of substance:

Product details:

Trade name: R-1 and R-22 Ink

Application of the substance / the preparation Printing inks

Manufacturer/Supplier:

Diagraph MSP, The Hitt Companies, Inc.
www.HittMarking.com

National Stencil Marking & Stenciling Products Division
www.NationalStencil.com

The Hitt Companies, Inc. National Stencil Marking & Stenciling Products Division

3231 W. MacArhur Blvd.

Santa Ana, CA 92704

USA

Customer Sales & Service:

714-979-1405

714-979-140 Fax

Information Department: Sales@HittCompanies.com@HittCompanies.com

Emergency information:

 

 

Contact Infotrac: (800) 969-6699 (US only)

International: +1 714 979 1405

2 Composition/Data on components:

 

Chemical characterization

Description: Mixture of the substances listed below with nonhazardous additions.

Dangerous components:

123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%

123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%

111-46-6 Diethylene glycol 0-5%

Additional information For the wording of the listed risk phrases refer to section 16.

 3 Hazards identification

Hazard description:

Irritant

Irritant

Information pertaining to particular dangers for man and environment:

The product has to be labelled due to the calculation procedure of the "General Classification

The product has to be labelled due to the calculation procedure of the "General Classification

guideline for preparations of the EU" in the latest valid version.

Irritating to eyes.

To avoid risks for humans and environment obtain instructions.

Classification system

The classification was made according to the latest editions of international substances lists, and

The classification was made according to the latest editions of international substances lists, and

expanded upon from company and literature data.

NFPA Ratings (scale 0-4)

Printing inks Diagraph MSP, an ITW Company, Mixture of the substances listed below with nonhazardous additions. 123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%For the wording of the listed risk phrases refer to section 16. IrritantThe product has to be labelled due to the calculation procedure of the "General ClassificationThe classification was made according to the latest editions of international substances lists, and

Printing inks Diagraph MSP, an ITW Company, Mixture of the substances listed below with nonhazardous additions. 123-42-2 4-hydroxy-4-methylpentan-2-one 80-100%For the wording of the listed risk phrases refer to section 16. IrritantThe product has to be labelled due to the calculation procedure of the "General ClassificationThe classification was made according to the latest editions of international substances lists, and

Printing inks msds@diagraphmsp.com Mixture of the substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section 16.

Printing inks msds@diagraphmsp.com Mixture of the substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section 16.

0

Health = 2

Fire = 2

Reactivity = 0

HMIS Rating (scale 0-4)
REACTIVITY

2

2

0

Health - 2

Flammability - 2

Reactivity - 0

Routes of Entry

Ingestion

Ingestion

Inhalation

(Contd. on page 2)

USA

Page 2/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

Trade name:

R-1 and R-22 Ink
(Contd. of page 1) Target Organs Eyes

Irritancy

Eyes

Eyes

Respiratory Tract

Skin

Sensitizing Capability None known

Reproductive Effects
None known Cancer Information Not known to be carcinogenic.

4 First aid measures

After inhalation Supply fresh air; consult doctor in case of complaints.

After skin contact Generally the product does not irritate the skin.

After eye contact

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Rinse opened eye for several minutes under running water. Then consult a doctor.

After swallowing

If swallowed, do not induce vomiting: seek medical advice immediately and show this container or

If swallowed, do not induce vomiting: seek medical advice immediately and show this container or

label

5 Fire fighting measures

Suitable extinguishing agents

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant

foam.

Protective equipment: No special measures required.

6 Accidental release measures

Person-related safety precautions: Not required.

Measures for environmental protection:

Inform respective authorities in case of seepage into water course or sewage system.

Inform respective authorities in case of seepage into water course or sewage system.

Measures for cleaning/collecting:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Ensure adequate ventilation.

7 Handling and storage

Handling

Information for safe handling:

Ensure good ventilation/exhaustion at the workplace.

Ensure good ventilation/exhaustion at the workplace.

Prevent formation of aerosols.

Wash hands thoroughly after handling.

Information about protection against explosions and fires: No special measures required.

Storage

Requirements to be met by storerooms and receptacles: No special requirements.

Information about storage in one common storage facility: Not required.

Further information about storage conditions: Keep receptacle tightly sealed.

Maximum storage temperature: 120 F (49 C)

Minimum storage temperature 35 F (2 C)

Eyes None known None known Not known to be carcinogenic. Supply fresh air; consult doctor in case of complaints. Generally the product does not irritate the skin. No special measures required. Not required. No special measures required. No special requirements. Not required. Keep receptacle tightly sealed. 120 F (49 C) 35 F (2 C)

USA

(Contd. on page 3)

Page 3/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

Trade name:

R-1 and R-22 Ink

(Contd. of page 2)

DR

8 Exposure controls and personal protection

Additional information about design of technical systems: No further data; see item 7.

Components with limit values that require monitoring at the workplace:

123-42-2 4-hydroxy-4-methylpentan-2-one

PEL

PEL

REL

TLV

240 mg/m³, 50 ppm

240 mg/m³, 50 ppm

238 mg/m³, 50 ppm

111-46-6 Diethylene glycol

WEEL 10 mg/m³

62-53-3 aniline

PEL

REL

TLV

19 mg/m³, 5 ppm

and Homologues; Skin

and Homologues; LFC

7.6 mg/m³, 2 ppm

Skin; BEI

Personal protective equipment

General protective and hygienic measures

Keep away from foodstuffs, beverages and feed.

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing

Wash hands before breaks and at the end of work.

Avoid contact with the eyes.

Avoid contact with the eyes and skin.

Breathing equipment:

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer

exposure use respiratory protective device that is independent of circulating air.

Protection of hands:

Protective gloves.

Protective gloves.

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

Material of gloves

Butyl rubber, BR

Butyl rubber, BR

Nitrile rubber, NBR

Natural rubber, NR

PVA gloves

Neoprene gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of

quality and varies from manufacturer to manufacturer. As the product is a preparation of several

substances, the resistance of the glove material can not be calculated in advance and has therefore to

be checked prior to the application.

Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and has

The exact break through time has to be found out by the manufacturer of the protective gloves and has

to be observed.

Not suitable are gloves made of the following materials:

Leather gloves

Leather gloves

PVC gloves

(Contd. on page 4)

No further data; see item 7.

USA

Page 4/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

Trade name:

R-1 and R-22 Ink

(Contd. of page 3)

 

 

Eye protection:

Tightly sealed goggles.

Tightly sealed goggles.

9 Physical and chemical properties:

 

General Information

Form:

Liquid

Color:

According to product specification

According to product specification

Odor:

Characteristic

Change in condition

Melting point/Melting range:

undetermined

Boiling point/Boiling range:

150°C (302°F)

150°C (302°F) Flash point: 56°C (133°F)

Ignition temperature: 620°C (1148°F)

Auto igniting: Product is not selfigniting.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:

Lower:

1.4 Vol %

Upper:

8.1 Vol %


8.1 Vol % Vapor pressure at 20°C (68°F): 1.1 hPa (1 mm Hg)

Density at 20°C (68°F): 0.96 g/cm³

Solubility in / Miscibility with

Water:

Partly miscible

Partly miscible

Solvent content:

Organic solvents:

94.8 %

Solids content: 5.0 %

10 Stability and reactivity

 

 

Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.

No decomposition if used according to specifications.Dangerous reactions No dangerous reactions known

Dangerous products of decomposition: No dangerous decomposition products known

11 Toxicological information

 

Acute toxicity:

Primary irritant effect:

on the skin: No irritant effect.

on the eye: Irritating effect.

Sensitization: No sensitizing effects known.

Additional toxicological information:

The product shows the following dangers according to internally approved calculation methods for

The product shows the following dangers according to internally approved calculation methods for

preparations:

(Contd. on page 5)

 

Tightly sealed goggles.56°C (133°F) 620°C (1148°F) 1.1 hPa (1 mm Hg) 0.96 g/cm³ Partly miscible No decomposition if used according to specifications.No dangerous reactions known No dangerous decomposition products known No irritant effect. Irritating effect. No sensitizing effects known. The product shows the following dangers according to internally approved calculation methods for

USA

Page 5/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

Trade name:

R-1 and R-22 Ink

(Contd. of page 4)

DR

Irritant

13 Disposal considerations

Product:

Recommendation

Must not be disposed of together with household garbage. Do not allow product to reach sewage

Must not be disposed of together with household garbage. Do not allow product to reach sewage

system.

Comply with all Federal, State, and Local regulations regarding disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

Disposal must be made according to official regulations.

Comply with all Federal, State, and Local regulations regarding disposal.

14 Transport information

DOT regulations: Non-regulated Material

Hazard class: 3

Identification number: UN1210

Packing group: III

ERG # 129

Proper shipping name (technical name): PRINTING INK

Label 3

Remarks: Note: For domestic GROUND shipments for non-bulk

packaging (119 gallons or less), this material may be

classified as a 'COMBUSTIBLE' under 49 CFR 173.150(f).

Therefore no labels or hazardous materials shipping papers

are required for domestic ground shipments for non-bulk

packaging of this product.

Land transport ADR/RID (cross-border)

 ADR/RID class: 3 Flammable liquids

3 Flammable liquids

 Danger code (Kemler): 30

 UN-Number: 1210

 Packaging group: III

Description of goods: 1210 PRINTING INK (not viscous)

1210 Printing ink

Maritime transport IMDG:

 MDG Class: 3

3

UN Number: 1210

Label 3

Packaging group: III

EMS Number: F-E,S-D

Marine pollutant: No

(Contd. on page 6)

USA

Page 6/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

Trade name:

 

R-1 and R-22 Ink (Contd. of page 5)

Propper shipping name: PRINTING INK

Air transport ICAO-TI and IATA-DGR:

 ICAO/IATA Class: 3

3

UN/ID Number: 1210

Label 3

Packaging group: III

Propper shipping name: PRINTING INK

15 Regulations

ancerogenity categories

EPA (Environmental Protection Agency)

62-53-3 aniline B2

62-53-3 aniline B2

IARC (International Agency for Research on Cancer)

62-53-3 aniline 3

62-53-3 aniline 3

NTP (National Toxicology Program)

None of the ingredients is listed. 

None of the ingredients is listed. 

TLV (Threshold Limit Value established by ACGIH)

62-53-3 aniline A3

62-53-3 aniline A3

MAK (German Maximum Workplace Concentration)

62-53-3 aniline 4

62-53-3 aniline 4

NIOSH-Ca (National Institute for Occupational Safety and Health)

62-53-3 aniline

62-53-3 aniline

OSHA-Ca (Occupational Safety & Health Administration)

62-53-3 aniline

62-53-3 aniline

Product related hazard information:

The product has been classified and marked in accordance with directives on hazardous materials.

The product has been classified and marked in accordance with directives on hazardous materials.

Hazard symbols:

Irritant

Irritant

Risk phrases:

Irritating to eyes.

Irritating to eyes.

Safety phrases:

Keep out of the reach of children.

Keep out of the reach of children.

Do not breathe gas/fumes/vapour/spray.

Avoid contact with skin and eyes.

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Do not empty into drains, dispose of this material and its container at hazardous or special waste

collection point

If swallowed, seek medical advice immediately and show this container or label.

Special labeling of certain preparations:

To avoid risks for humans and environment obtain instructions.

To avoid risks for humans and environment obtain instructions.

(Contd. on page 7)

 

3 62-53-3 aniline B262-53-3 aniline 3None of the ingredients is listed. 62-53-3 aniline A362-53-3 aniline 462-53-3 anilineIrritant

USA

Page 7/7

Material Safety Data Sheet

acc. to ISO/DIS 11014

09/23/2009 Revision date: 07/21/2009

Trade name:

R-1 and R-22 Ink

(Contd. of page 6)

(Contd. of page 6)

 

 

National regulations

Other regulations, limitations and prohibitive regulations

OSHA Regulations

Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed

Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed

OSHA Specifically Regulated Substance (29 CFR 1910.): Not listed

Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III, Section 313:

This product does not contain chemicals listed as toxic chemicals at levels which require reporting

This product does not contain chemicals listed as toxic chemicals at levels which require reporting

under SARA Title III Section 313.

CONEG:

This product meets CONEG and RoHS legislation for low levels of Lead, Cadmium, Mercury,

This product meets CONEG and RoHS legislation for low levels of Lead, Cadmium, Mercury,

Hexavalent Chrome, and Brominated flame retardants.

Lead (Pb) < 10 ppm

Mercury (Hg) < 5 ppm

Hexavalent Chrome (CR+6) < 7 ppm

Total Bromine (Br) 52 ppm

Cadmium (Cd) < 7 ppm

Toxic Substances Control Act TSCA Status:

All components of this product are listed in the EPA's Inventory of Chemical Substances as required

All components of this product are listed in the EPA's Inventory of Chemical Substances as required

under the Toxic Substances Control Act (TSCA).

California Proposition 65 (Chemicals known to cause cancer):

62-53-3 aniline

62-53-3 aniline

California Proposition 65 (Chemicals known to cause reproductive toxicity):

This product contains no ingredients on the California Proposition 65 known to cause reproductive

This product contains no ingredients on the California Proposition 65 known to cause reproductive

toxicity.

16 Other information:

 

This information is based on our present knowledge. However, this shall not constitute a guarantee for

any specific product features and shall not establish a legally valid contractual relationship.

Department issuing MSDS: Chemistry

MSDS Created By: Peter Gimse

File: 124

Revision Information (All previous revisions obsolete):

This Revision: 7/25/2008 Section 1: Added R-22 and Removed Product Numbers; Section 2: Updated

Health Rating, Section 9: Changed Color to reflect addition of red; Section 15: Updated CONEG,

RoHs, and Prop 65

Previous Revisions:

1/1/2005 Removed Hexylene Glycol

2/26/2002 Updated Company Info

8/11/2000 Section 1: updated product numbers. Section 14: Added ERG#. Corrected IMDG page

number

09/20/1999 Initial Release

Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listedThis product does not contain chemicals listed as toxic chemicals at levels which require reportingThis product meets CONEG and RoHS legislation for low levels of Lead, Cadmium, Mercury,All components of this product are listed in the EPA's Inventory of Chemical Substances as required62-53-3 anilineThis product contains no ingredients on the California Proposition 65 known to cause reproductive

 

USA The Hitt Companies, Inc. www.HittMarking.com   USA